Page:Treatise on poisons in relation to medical jurisprudence, physiology, and the practice of physic (IA treatiseonpoison00chriuoft).pdf/415

 *stances, I found the cistern singularly clean and free of incrustation, and the water quite free of lead. The composition of the water explained these facts. It contains a 4,900th of salts, a large proportion of which consists of carbonates of lime and magnesia.

The water of Edinburgh is another example of spring water nearly destitute of action on lead. But it is not so completely inactive as the water of Airthrey. In four ounces of water three bright rods weighing fifty-seven grains lost in seven days a 250th of a grain, in twenty-one days a 100th, in thirty-five days a 66th, and in sixty-three days a 59th of a grain. In seven days the lead was hardly tarnished at all, and not a speck of powder could be seen in the water, or on the glass. In twenty-one days, but still more in thirty-five or sixty-three days, the lead was uniformly dull; and on the surface of the water, as well as on the bottom of the glass, and on the side where left dry by the evaporation of the water, there were many white, filmy specks, which became black with the hydrosulphate of ammonia. In another experiment 145 grains of lead kept for six months in six ounces of Edinburgh water, which was filled up as it evaporated, lost a fifteenth of a grain; and the white incrustation on the bottom and sides of the glass gave a large proportion of black precipitate when scraped together and treated with hydrosulphate of ammonia. These experiments are of some practical importance. For they show that the impregnation which the water of Edinburgh can receive in a few days from being kept in lead is so small as to be barely perceptible by the nicest analysis; but that the impregnation may be material if the same portion of water is kept in lead for a considerable length of time. Hence the perfect safety of the leaden cisterns and service-pipes used in this city. The same portion of water rarely remains in them above a single day, and therefore cannot become impregnated in a degree that is appreciable by the nicest examination. Dr. Thomson of Glasgow, in an interesting inquiry made in 1815 into the purity of the water which supplies Tunbridge, has stated that, when he lived in Edinburgh some years before, he could always detect a minute trace of lead suspended in the water, which at that time was brought six miles in leaden pipes. I presume it is owing to the main pipes being now made of iron that this impregnation no longer exists. For I have found that the residue of two gallons of water, very carefully collected by gentle evaporation of successive portions in a small vessel, did not furnish the slightest trace of lead, when strongly heated with black flux and then acted on by nitric acid. The feeble action of the Edinburgh water on lead arises from the salts it holds in solution. It contains about a 12,000th part of its weight of solid matter, of which about two-thirds are carbonate of lime, and one-third consists of the sulphates and muriates of soda, lime, and magnesia.