Page:The Liquefaction of Gases.djvu/47

Rh I have not yet resolved this irregularity, but believe there are two or more substances, physically, and perhaps occasionally chemically different, in olefiant gas; and varying in proportion with the circumstances of heat, proportions of ingredients, &c., attending the preparation.

The fluid affected the resin of the gauge graduation, and probably also the resin of the cap cement, though slowly.

Hydriodic acid.—This substance was prepared from the iodide of phosphorus by heating it with a very little water. It is easily condensable by the temperature of a carbonic acid bath; it was redistilled, and thus obtained perfectly pure.

The acid may be obtained either in the solid or liquid, or (of course) in the gaseous state. As a solid it is perfectly clear, transparent, and colourless; having fissures or cracks in it resembling those that run through ice. Its solidifying temperature is nearly -60° ., and then its vapour has not the pressure of one atmosphere; at a point a little higher it becomes a clear liquid, and this point is close upon that which corresponds to a vaporous pressure of one atmosphere. The acid dissolves the cap cement and the bitumen of the gauge graduation; and appears also to dissolve and act on fat, for it leaked by the plug of the stop-cock with remarkable facility. It acts on the brass of the apparatus, and also on the mercury in the gauge. Hence the following results as to pressures and temperatures are not to be considered more than approximations:—

Hydrobromic acid.—This acid was prepared by adding