Page:Radio-activity.djvu/273

 Giesel has recorded some interesting observations of the effect of the radium emanation on a screen of phosphorescent zinc sulphide. When a few centigrams of moist radium bromide were placed on a screen any slight motion of the air caused the luminosity to move to and fro on the screen. The direction of phosphorescence could be altered at will by a slow current of air. The effect was still further increased by placing the active material in a tube and blowing the air through it towards the screen. A screen of barium platino-cyanide or of Balmain's paint failed to give any visible light under the same conditions. The luminosity was not altered by a magnetic field, but it was affected by an electric field. If the screen were charged the luminosity was more marked when it was negative than when it was positive.

Giesel states that the luminosity was not equally distributed, but was concentrated in a peculiar ring-shaped manner over the surface of the screen. The concentration of luminosity on the negative, rather than on the positive, electrode is probably due to the excited activity, caused by the emanation, and not to the emanation itself, for this excited activity is concentrated chiefly on the negative electrode in an electric field (see chapter ).

An experiment to illustrate the phosphorescence produced in some substances by the rays from a large amount of emanation is described in section 165.

148. Curie and Debierne have investigated the emanation from radium, and the excited activity produced by it. Some experiments were made on the amount of emanation given off from radium under very low pressures. The tube containing the emanation was exhausted to a good vacuum by a mercury pump. It was observed that a gas was given off from the radium which produced excited activity on the glass walls. This gas was extremely active, and rapidly affected a photographic plate through the glass. It caused fluorescence on the surface of the glass and rapidly blackened it, and was still active after standing ten days. When spectroscopically examined, this gas did not show any new lines, but generally those of the spectra of carbonic acid, hydrogen,