Page:Radio-activity.djvu/248

 or Ur X does not, of itself, prove directly that a material constituent responsible for the activity has been chemically separated. For example, in the case of the separation of Th X from thorium, it might be supposed that the non-thorium part of the solution is rendered temporarily active by its association with thorium, and that this property is retained through the processes of precipitation, evaporation, and ignition, and finally manifests itself in the residue remaining. According to this view it is to be expected that any precipitate capable of removing the thorium completely from its solution should yield active residues similar to those obtained from ammonia. No such case has, however, been observed. For example, when thorium nitrate is precipitated by sodium or ammonium carbonate, the residue from the filtrate after evaporation and ignition is free from activity and the thorium carbonate obtained has the normal amount of activity. In fact, ammonia is the only reagent yet found capable of completely separating Th X from thorium. A partial separation of the Th X can be made by shaking thorium oxide with water owing to the greater solubility of Th X in water.

Thorium and uranium behave quite differently with regard to the action of ammonia and ammonium carbonate. Ur X is completely precipitated with the uranium in an ammonia solution and the filtrate is inactive. Ur X is separated by ammonium carbonate, while Th X under the same conditions is completely precipitated with the thorium. The Ur X and the Th X thus behave like distinct types of matter with well-marked chemical properties quite distinct from those of the substances in which they are produced. The removal of Ur X by the precipitation of barium is probably not directly connected with the chemical properties of Ur X. The separation is probably due to the dragging down of the Ur X with the dense barium precipitate. Sir William Crookes found that the Ur X was dragged down by precipitates when no question of insolubility was involved, and such a result is to be expected if the Ur X exists in extremely minute quantity. It must be borne in mind that the actual amount of the active constituents Th X and Ur X, separated from thorium and uranium, is probably infinitesimal, and that the greater proportion of the residues is due to impurities present