Page:Proceedings of the Royal Society of London Vol 60.djvu/92

Rh after being cleaned, was then very carefully filled with the purified mercury, and by running the mercury through a spiral several times, all air bubbles and air film were finally removed. Into the wider ends of the spiral, amalgamated copper electrodes were introduced, consisting of copper wire 4'4 mm. in diameter; the wider terminal ends of the spiral were then closed by paraffined corks to keep the copper electrodes in position. This spiral, full of mercury, was placed in a test-tube, and paraffin wax cast round it so as to enclose it entirely, leaving only the copper electrodes protruding. In order to determine the temperature of the mercury in the glass spiral tube, a platinum wire, the resistance of which was known at all temperatures down to the temperature of liquid air, was also embedded in the paraffin wax closely in contact with the glass spiral, and proper electrodes brought out to enable the resistance of this platinum wire to be determined. This mass of paraffin wax was then cooled down in a vacuum vessel kept filled up with liquid air until the whole mass reachedv the temperature of the liquid air. The glass spiral and thermometer enclosed in wax was then removed from the bath of liquid air and placed in a vacuum-jacketed test-tube, in order that it might warm up with extreme slowness to the ordinary temperature of the air.

Having in this manner cooled the mass of paraffin enclosing the glass spiral filled with mercury and the platinum resistance wire entirely to the temperature of liquid air, a series of observations were taken with the aid of two observers, one measuring the resistance of the mercury by a Wheatstone’s Bridge, while at the same time the other observer at another slide wire bridge measured the resistance of the platinum wire, these observations being taken quite simultaneously, and continued whilst the mass heated up from —197‘9° (platinum temperature) to 0°. All proper corrections were then applied to correct for the resistance of the connecting wires and the bridge temperature ; and the observed resistance of the platinum wire employed was corrected to determine from its resistance temperatures in terms of the standard platinum thermometer employed by us in our investigations on the thermo-electric power of metals and alloys (see Dewar and Fleming, ‘Phil. Mag.,’ July, 1895, p. 95). This standard thermometer has always been denoted by the letter Px. The following table shows the corrected resistance of the mercury column and the corresponding platinum temperatures, as also the specific resistance of the mercury calculated from the accepted resistivity at 0° C. :—