Page:Popular Science Monthly Volume 55.djvu/49

Rh are used it is only necessary to allow them to pass rapidly into the gaseous state, when more or less heat is absorbed. This is the basis for the use of liquid ammonia in the manufacture of ice. A vessel containing the liquid ammonia is placed in another containing water. The inner vessel being opened, the liquid ammonia is rapidly converted into the gas; heat is absorbed from the water; it freezes. When a vessel containing liquid carbonic acid is opened so that the gas that is formed escapes through a small valve, so much heat is absorbed that a part of the liquid carbonic acid is itself frozen. In this case the substance is present in all three states of aggregation—the solid, the liquid, and the gaseous. The use of a mixture of ether and solid carbonic acid as a freezing mixture has already been referred to. Its value depends, of course, principally upon the fact that solid carbonic acid is liquefied, and the liquid then converted into gas, both of which operations involve absorption of heat.

We are now prepared to understand the important experiments of Cailletet and of Pictet, the results of which were published in 1877. It should be said that they worked independently of each other—Cailletet in Paris and Pictet in Geneva. Pictet liquefied carbonic acid and sulphur dioxide by pressure. The liquid carbonic acid was passed through a tube that was surrounded by liquid sulphur dioxide boiling in a partial vacuum. The liquid carbonic acid thus cooled was then boiled under diminished pressure in a jacket surrounding a tube in which the gas to be liquefied was contained under high pressure. When this gas was allowed to escape from a small opening its temperature was so reduced by the expansion that a part of it was liquefied in the tube and passed off as a liquid. Cailletet worked in essentially the same way, but on a smaller scale. Neither of these experimenters liquefied oxygen or nitrogen on the large scale, but they pointed out the way that must be followed in order that success may be attained. They destroyed the belief in "permanent" gases.

Later experimenters in this field are Wroblewski, Olszewski, and Dewar, who have been interested mainly in the purely scientific side of the problem, while Linde in Germany, Hampson in England, and Tripler in the United States have their minds on the practical side. Notwithstanding the low temperatures involved in the experiments, a number of heated discussions have been carried on in the scientific journals touching the question of priority. To the unprejudiced observer it appears that all of those named above are entitled to credit. They have all helped the cause along, but just how to apportion the credit no one knows. In a general way, however, some of the results obtained by each in turn should be given. Wroblewski and Olszewski have carried on the work begun by Cailletet and Pictet,