Page:Popular Science Monthly Volume 55.djvu/47

Rh gases, but for some gases pressures very much higher and temperatures very much lower are required. Faraday himself succeeded in liquefying all the gases then known except oxygen, hydrogen, nitrogen, nitric oxide, and marsh gas. He subjected oxygen to a pressure of about one thousand pounds to the square inch, or nearly seventy atmospheres, but it showed no signs of liquefaction. Later experimenters increased the pressure to four thousand pounds to the square inch, with no better results, so that it is not surprising that it came to be held that some gases are permanent.

Within comparatively recent years several gases have been liquefied on the large scale by means of pressure. These are ammonia, carbonic acid, nitrous oxide, and chlorine. Ammonia is used for producing low temperatures, as in breweries and in cold-storage plants and in the manufacture of ice; carbonic acid, for fire extinguishers and for charging beer with the gas; nitrous oxide, for producing anæsthesia; and chlorine in connection with several branches of chemical manufacture. The production of low temperatures by means of liquid ammonia and of liquid carbonic acid will be more fully dealt with further on, when the principles involved will be briefly presented. It is to be borne in mind that these substances are liquefied by means of pressure alone, at temperatures that are easily reached, so that it appears that by mechanical pressure it is possible to produce low temperatures. In 1869 an important fact was discovered by Andrews. It was that for every gas there is a temperature above which it is impossible to liquefy it by pressure. Thus, if chlorine is at any temperature above 146° C. (294° F.) it can not be liquefied. This temperature is called the "critical temperature" of chlorine. The pressure to which the gas must be subjected at the "critical temperature" in order that the gas may be liquefied is called the "critical pressure." In the case of chlorine this is 93.5 atmospheres. Now, the critical temperature of the gases that were called permanent gases are very low—lower than could be reached by the means at the command of earlier experimenters. The critical temperature of oxygen, for example, is -118.8° C. (-182° F.), while that of nitrogen is -146° C. (-230° F.). The critical pressures are 50.8 and 35 atmospheres respectively. As there is no difficulty in obtaining these pressures, the problem of liquefying oxygen and nitrogen and air resolves itself into finding a method of producing temperatures below the critical temperatures of these gases.

It is well known that a temperature somewhat below the freezing point of water can be produced artificially by mixing ice and salt. The ordinary ice-cream freezer is a familiar application of this method of producing cold. Other freezing mixtures that are sometimes used consist of calcium chloride and snow, that gives the