Page:NIOSH Manual of Analytical Methods - 9200.pdf/5

 CHLORINATED AND ORGANONITROGEN HERBICIDES (HAND WASH): METHOD 9200 - Page 5 of 11

TABLE 1. SYNONYMS, FORMULA, MOLECULAR WEIGHT, PROPERTIES Empirical Formula

Molecular Weight

Solubility in Water (mg/L)

LD50 mg/kg

Alachlor 2-Chloro-N-(2,6-diethylphenyl)-N-(methoxymethyl)acetamide CAS #15972-60-8 RTECS AE1225000

C14H20ClNO2

269.77

Colorless crystals; d 1.133 g/mL@ 25 C; MP 39.541.5 C; VP 0.0029 Pa (2.2 x 10-5 mm Hg) @ 25 C

140 @23 C

1200

Atrazine 6-Chloro-N-ethyl-N’-isopropyl-1,3,5-triazine-2,4-diamine CAS # 1912-24-9 RTECS XY5600000

C8H14ClN5

215.68

Colorless crystals; MP 173-175 C; VP 4 x 10-5 Pa (3.0 x 10-7 mm Hg) @ 20 C

70 @ 25 C

1780

Cyanazine 2[[4-chloro-6-(ethylamino)-1,3,5-triazin-2-yl]amino]-2methylpropionitrile CAS #21725-46-2 RTECS UG1490000

C9H13ClN6

240.69

White crystalline solid; MP 167.5-169 C; VP 2.1 x 10-7 Pa (1.6 x 10-9 mm Hg) @ 20 C

171 @ 25 C

182

2,4-D acid 2,4-Dichlorophenoxyacetic acid CAS #94-75-7 RTECS AG6825000

C8H6Cl2O3

221.04

White powder; MP 140.5 C; <10-5 Pa (<7.5 x 10-8 mm Hg) @ 25 C

almost insoluble

375

2,4-D, ME 2,4-Dichorophenoxyacetic acid, methyl ester CAS #1928-38-7

C9H8Cl2O3

235.07

2,4-D, BE 2,4-Dichlorophenoxyacetic, 2-butoxyethyl ester CAS #1929-73-3 RTECS AG7700000

C14H18Cl2O4

321.20

150

2,4-D, EH 2,4-2,4-Dichlorophenoxyacetic acid, 2-ethylhexylester CAS #1928-43-4

C16H22Cl2O3

333.25

300 1000

Metolachlor 2-Chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1methylethyl)acetamide CAS #51218-45-2 RTECS AN3430000

C15H22ClNO2

283.80

Odorless tan liquid; 0.0017 Pa (1.3 x 10-5 mm Hg) @ 20 C

530 @ 20 C

2780

Simazine 6-Chloro-N,N’-diethyl-1,3,5-trazine-2,4-diamine CAS #122-34-9 RTECS XY5250000

C7H12ClN5

201.66

Crystals; MP 225 -227 C; 8.1 x 10-7 Pa (6.1 x 10-7 mm Hg) @ 20 C

3.5 @ 20 C

5000

Name / Synonym

Physical Properties

TABLE 2. USEFUL GAS CHROMATOGRAPHIC COLUMNS AND CONDITIONS (1)

NIOSH Manual of Analytical Methods (NMAM), Fourth Edition

TWA (mg/m3)

NIOSH 5 ACGIH 5

NIOSH 10 ACGIH 10 OSHA 10