Page:NIOSH Manual of Analytical Methods - 6009.pdf/5

 MERCURY: METHOD 6009, Issue 2, dated 15 August 1994 - Page 5 of 5 1. 2. 3. 4. 5.

6.

The valve should direct the vented vapors to a hood or to a mercury scrubber system. When the valve is opened to "Vent" the peristaltic pump should draw room air. Place a Hopcalite tube in the air intake to eliminate any mercury that may be present. Adjust the peristaltic pump to a flow that will create a steady stream of bubbles in the BOD bottle, but not so great that solution droplets enter the tubing to the quartz cell. If water vapor condenses in the quartz cell, heat the cell slightly above room temperature by wrapping it with a heating coil and attaching a variable transformer. The bubbler consists of a glass tube with a bulb at the bottom, slightly above the bottom of the BOD bottle. The bulb contains several perforations to allow air to escape into the solution (in a stream of small bubbles). A second tube is provided to allow the exit of the vapor. The open end of the second tube is well above the surface of the liquid in the bottle. The two tubes are fixed into a stoppering device (preferably ground glass) which fits into the top of the bottle. A coarse glass frit can be used in place of the bulb on the first tube. However, it is more difficult to prevent contamination when a frit is used. Replace the flexible tubing (Tygon or equivalent) used to connect the bubbler, cell, and pump periodically to prevent contamination from adsorbed mercury.

NIOSH Manual of Analytical Methods (NMAM), Fourth Edition, 8/15/94