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 ALIPHATIC ALDEHYD ES: METHO D 2018, Issue 1, dated 15 March 2003 - page 6 of 10 the HPLC when the mobile phase consisted of 66:34 acetonitrile:water at 1.3 mL/m in. Retention times of valeraldehyde-DNPH and isovaleraldehyde-DNPH were 7.82 and 7.32 m in, respectively. Although two sharp peak s were observed, th e separatio n was only partial. This method can be used with SKC aldehyde samplers (DNPH-coated silica gel tubes, catalogue No. 226119) for aceta ldehyde, propionaldehyde, valeraldehyde, and isovaleraldehyde with modifications (see APP EN DIX ).

REFERENCES: [1]

[2]

[3]

[4]

[5]

[6]

[7] [8] [9]

[10] [11] [12] [13]

[14]

Tucker SP [2002]. Aliphatic Aldehydes Backup Data Report for method 2018 for acetaldehyde, propionaldehyde, valeraldehyde, and isovaleraldehyde (butyraldehyde and crotonaldehyde), C incinnati, OH: unpublished report. National Institute for Occupational Safety and Health, DART. Kleindienst TE, Corse EW, and Blanchard FT [1998]. Evaluation of the Performance of DNPH-Coated Silica Gel and C 18 Cartridges in the Measurement of Formaldehyde in the Presence and Absence of Ozo ne. E nviron m enta l Scien ce & Te chn ology, 32(1), 124-130. ASTM [2001]. Method D5197-97, Standard Test Method for Determination of Formaldehyde and Other Carbonyl Com pounds in Air (Active Sampler Methodology). Atmospheric Analysis, Occupational Health and Safety, Protective Clothing, 1103, W est Conshohocken, PA: American Society for Testing and Mate rials, A ST M Inte rnatio nal. U.S. EPA [1999]. Compendium Method TO-11A: Determination of Formaldehyde in Ambient Air Using Adsorbent Cartridge Followed by High Performance Liquid Chromatography (HPLC), Compendium of Methods for the De term ination of T oxic O rganic C om pounds in Am bient Air, Second Edition, U.S. Environmental Protection Agency, Center for Environmental Research Information, Office of Research and Development, W ashington, DC. EPA/625/R-96/010b. NIOSH [1994]. Acetaldehyde by GC, m etho d 2538. In: E ller PM, Cassinelli ME, eds. NIOSH M anual of Ana lytical Method s, 4 th ed., U.S. De partm ent of He alth and H um an Servic es, Pu blic Health Service, Centers for Disease Control and Prevention, National Institute for Occupational Safety and Health, Cincinnati, OH. DHHS (NIOSH) Publication No. 94-113. NIOSH [1994]. Acetaldehyde by Bubbler and HPLC, method 3507. NIOSH Manual of Analytical Methods, 4 th ed., Eller PM, Cassinelli ME, eds., U.S. Department of Health and Hu m an Servic es, Pu blic He alth Service, Centers for D isease C ontro l and P reve ntion, N ationa l Institute for Occu pation al Safety and Health, Cincinnati, OH. DHHS (NIOSH) Publication No. 94-113. OSHA [1990]. Acetaldehyde, method 68, OSHA A nalytical Methods Ma nua l, 2 nd ed., U.S. Department of Labor, Occupational Safety and Health Administration, Salt Lake City, UT. OSHA [1990]. Valeraldehyde, method 85, OSHA Analytical Me thod s M anu al, 2 nd ed., U.S. Department of Labor, Occupational Safety and Health Administration, Salt Lake City, UT. NIOSH [1991]. Current Intelligence B ulletin 55, Carciongen icity of Acetaldehyde and Malonaldehyde, and Mutagenicity of Related Low-Molecular-W eight Aldehydes. U.S. Department of Health and Human Services, Pub lic Health Service, Centers for Disease Control, N ationa l Institute fo r Occu pation al Safety and Health, Cincinnati, OH. DHHS (NIOSH) Publication No. 91-112. Pacak ova V, Ko nas M, and K otvalova V [1985]. Reaction Gas Chrom atography: Study of the Photodecomposition of Selected Substances, Chromatographia 20 (3), 164-172. Otson R and Fellin P [1998]. A Review of Techniques for Measurement of Airborne Aldehydes. Science of th e T otal Environ m ent, 77 (2/3), 95-131. Risner CH [1995]. High Perform ance Liquid Ch rom ato graphic De term ination of M ajo r Carbonyl Co m pou nds from Various Sou rces in Am bient Air, J. C hrom atog r. Sci., 33 (4), 168-176. NIOSH [1994]. Formaldehyde by HPLC, m ethod 2016, issue 2, NIOSH Manual of Analytical Methods, 4 th ed., Eller PM, Cassinelli ME, eds., U.S. Department of Health and Human Services, Pub lic Health Service, Centers for Disease Control and Prevention, National Institute for Occupational Safety and Health, Cincinnati, OH. DHHS (NIOSH) Publication No. 94-113. NIOSH [1998]. NIO SH /OS HA Oc cup ationa l Hea lth Guidelines for Chem ical Hazards, U.S. Department of Health and Human Services, Public Health Service, Centers for D isease C ontro l, Nation al Institute for Oc cup ationa l Safe ty and H ealth, C incinn ati, OH. DHHS (NIOSH) Publication No. 88-118, Supplement 1-OHG. For sale by the Superintendent of Docum ents, U.S. Government Printing Office, W ashington, DC 20402.

NIOSH Manual of Analytical Methods (NMAM), Fourth Edition