Page:Experimental researches in chemistry and.djvu/242

1827.] stoppered bottles, two were put into basins and covered over with bibulous paper, and one was put into a basin and left open; all were set aside in an obscure place, and remained from July 16th to August 28th. Being then examined, the portions in the basins were found crystallized and dry; the crystals were large and flat, striated and imperfect, resembling those formed in a similar way from carbonate of soda. They were not small and acicular, were nearly alike in the three basins, and had effloresced only on a few minute points. A part of one portion, when dissolved, gave a solution having an alkaline taste, without any of the pungency of Labarraque's liquid; and when tested by turmeric paper, it reddened, but did not bleach it.

14. One of these portions, that had effloresced least, was selected, and being dissolved, was compared in bleaching power upon diluted sulphate of indigo, with one of the portions of solution that had been preserved in bottles. The former had scarcely any visible effect, though sulphuric acid was added to assist the action; a single measure of the indigo liquor coloured the solution permanently blue, whereas seventy-seven such measures were bleached by the portion from the bottle. Hence the process of slow crystallization had either almost entirely expelled the chlorine, or else had caused it to react upon the alkali, and by entering into strong chemical combination as chloride and chlorate, had rendered it inert as a bleaching or disinfecting agent.

15. From the appearance of the crystals there was no reason to expect the latter effect; but to put the question to the proof; one of the evaporated portions, and one of the fluid portions contained in the bottles, were acted upon by sulphuric acid, heat, and a current of air, in the manner already described (11), to separate the chlorine that had not combined as chloride or chlorate. They were then compared with an equal portion of the solution, which retained all its chlorine, nitrate of silver being used as before; the quantity of chloride indicated for the latter portion was 60 parts; whilst that of the fluid portion deprived of as much free chlorine as could be, by sulphuric acid and blowing, was 6 parts; and for the evaporated and crystallised portion, similarly cleared of free chlorine, only 1.5 part.