Page:Experimental researches in chemistry and.djvu/160

1825.], were found to be essentially requisite, in consequence of the delicacy of the means afforded by heat and turmeric paper for testing the presence of ammonia, or rather, of matter containing its elements. As a proof of this, it may be mentioned, that some sea sand was heated red-hot for half an hour in a crucible, and then poured out on to a copper-plate, and left to cool; when cold, a portion of it (about 12 grains) was put into a clean glass tube; another equal portion was put into the palm of the hand, and looked at for a few moments, being moved about by a finger, and then introduced by platina foil into another tube, care being taken to transfer no animal substance but what had adhered to the grains of sand: the first tube when heated yielded no signs of ammonia to turmeric paper, the second a very decided portion.

As a precaution, with regard to adhering dirt, the tubes used in precise experiments were not cleaned with a cloth or tow, but were made from new tube, the tube being previously heated red-hot, and air then drawn through it; and no zinc or potash was used in these experiments, except such as had been previously tried by having portions heated in a tube to ascertain whether when alone they gave ammonia.

It was then thought probable that the alkali might contain a minute quantity of some nitrous compound, or of a cyanide, introduced during its preparation. A carbonate of potash was therefore prepared from pure tartar, rendered caustic by lime calcined immediately preceding its use, the caustic solution separated by recantation from the carbonate of lime, not allowed to touch a filter or anything else animal or vegetable, and boiled down in clean flasks; but the potash thus obtained, though it yielded no appearance of ammonia when heated alone, always gave it when heated with zinc.

The water used in these experiment was distilled, and in cases where it was thought necessary was distilled a second, and even a third time. The experiments of Sir Humphry Davy show how tenaciously small portions of nitrogen are held by water, and that in certain circumstances the nitrogen may produce ammonia. I am not satisfied that I have been able to avoid this source of error.

At last, to avoid every possible source of impurity in the pot