Page:Encyclopædia Britannica, Ninth Edition, v. 21.djvu/60

Rh great rarity and value, while the latter is an aluminate of magnesium, inferior to the true ruby in hardness and much less esteemed as a gem stone. With ancient writers the confusion was even greater, for they appear to have classed together under a common name, such as the car- bunculus of Pliny or the av6pa of Greek writers, not only our two kinds of ruby but also garnets and other inferior stones of a brilliant fiery colour. By modern mineral- ogists it has come to be understood that when the word ruby is used without any qualifying prefix the true or Oriental stone is invariably indicated. The Oriental ruby, like all other varieties of corundum, crystallizes in the rhombohedral system; but, as it usually occurs as small pebbles or rounded fragments, the crystal- line form can rarely be traced. Its colour varies from deep cochineal to pale rose red, in some cases inclining to purple, the most valued tint being that known to experts as pigeon's blood colour. On exposure to a high tempera- ture the ruby becomes green, but regains its original colour on cooling a behaviour which is consistent with the sup- position that the stone owes its colour to the presence of oxide of chromium, and indeed in artificial rubies the required tint is always obtained by the use of some com- pound of chromium. When a ruby of the most esteemed colour is properly viewed through a dichroiscope, the colour is resolved into a carmine and an aurora red, or red inclining to orange. By this test the true ruby may be distinguished from spinel and garnet, since these minerals crystallize in the cubic system and therefore are not di- chroic. Another mode of distinction is suggested by the high density of corundum : the specific gravity of the true ruby reaches or even rises slightly above 4, and thus greatly exceeds that of either spinel or garnet. But perhaps the simplest test is afforded by its great hard- ness (H = 9): the sharp edge of a corundum crystal will readily scratch either a spinel or a garnet, but has no effect on a ruby. The true ruby has a very high index of refraction (/A = 1-78), and to this character is due the remarkable lustre of the polished stone. Mr Crookes lias shown that the ruby is brilliantly phosphorescent when subjected to radiant discharge in a properly ex- hausted vessel, and curiously enough the red light emitted is equally vivid whatever be the colour of the corundum under experiment. The microscopic structure of the ruby has been studied by Mr Sorby, who finds that the stone contains fluid cavities and numerous crystallized enclosures of other minerals (Proc, Roy. Soc., xvii., 1869. p. 291). The Oriental ruby is a mineral of very limited distribution, its principal localities being confined to the kingdom of Burmah. The most important ruby mines are situated at Kyat Pyen, about 70 miles to the north-east of Mandalay ; there are also mines at Mookop, a little farther north, and others in the Sagyin Hills, within 16 miles of Mandalay. In all these localities the rubies occur in association with sapphires and other precious stones, forming a gem-bearing gravel which is dug up and washed in very primitive fashion. By far the larger number of the rubies are of small size, and the larger stones are generally flawed. All rubies exceeding a certain weight were the property of the king of Burmah. The mines were jealously watched, and it was difficult for Europeans to obtain access to them ; but some of the Ava workings were visited and described many years ago by Pere Giuseppe d'Amato, and more recently those near Mandalay have been described by Mr Bredmeyer, who was officially connected with them (Ball). It is stated in the older works on mineralogy that rubies occur in the Capelan Mountains near Syrian, in Pegu. In peninsular India there are but few localities that yield rubies, but they have been reported from the corundum mines of the Salem district in Madras and from Mysore. In Ceylon they occur with sapphires, but are rarer than those gems, and the Ceylon rubies are not usually of good colour. Rubies have been brought from Gandamak, in Afghanistan, but most of the stones reputed to be Afghan rubies are merely spinels. In 1871 some remarkable deposits of corundum were discovered by Col. C. W. Jenks in Macon co., North Carolina. Rubies, sapphires, and large pebbles of coarse corundum were found in the bud of a river near a large mass of serpentine which afterwards became known as Corundum Hill, and these pebbles were eventually traced to certain veins in the serpentine. The corundum occurred crystallized in situ, but was rarely of such a colour as would entitle it to be called ruby. Mr G. F. Kunz, who has lately written an article on American precious stones, states that rubies and sapphires have also been found at Vernon, New Jersey ; near Helena, Montana ; at Santa Fe New Mexico ; in southern Colorado ; and in Arizona. Australia has occasionally yielded true rubies, but mostly of small size and inferior quality. In Victoria they have been found in the drifts of the Beechworth gold fields and at the Berwick tin mine, Wallace's Creek ; while in New South Wales they occur at Mudgee, in the Cudgegong and some of its tributaries, and at Tumberumba, co. Wynyard. A magenta-coloured turbid ruby from Victoria is known under the name of " barklyite." The "star ruby" is a rather cloudy variety from Ceylon, exhibit- ing when cut en cabochcm, a luminous star of six rays, reflected from the convex surface of the stone. The largest ruby known in Europe is said to be one of the size of a small hen's egg, which was presented by Gustavus III. of Sweden to the empress of Russia on the occasion of his visit to St Petersburg. Rubies of larger size have been described by Tavernier and other Oriental travellers, but it is probable that in many cases spinels have been mistaken for true rubies. There seems no doubt that the great historic ruby set in the Maltese cross in front of the imperial state crown of England is a spinel. This stone was given to Edward the Black Prince by Pedro the Cruel, king of Castile, on the victory of Najera^ in 1367, and it was afterwards worn by Henry V. at the battle of Agiucourt, when it narrowly escaped destruction. The spinel ruby has been described in the article MINERALOGY (vol. xvi. p. 386, sp. 93). The spinels used for jewellery are mostly obtained in Burmah, where they occur as octahedral crystals or as water-worn pebbles in association with the true ruby, for which they are often mistaken. They are also found in the gem-bearing gravels of Ceylon, Victoria, and New South Wales. The delicate rose-pink variety known as balas ruby was worked for centuries in Badakhshan, but the operations appear to have been suspended of lato years. The mines are situated on the river Shighnan, a tributary of the Oxus. It is commonly said that the name "balas or " balash " is a corruption of Badakhshan, while others derive it from Balkh. The Oriental ruby has always been esteemed of far higher value than any other precious stone. A ruby of perfect colour, weighing five carats, is worth at the present day ten times as much as a diamond of equal weight (Streeter). As the weight of the stone increases, its value rapidly rises, so that rubies of exceptional size command enormous prices. There is consequently much tempta- tion to replace the true stone by spinel or garnet or even paste. By means of oxide of chromium an excellent imitation of the colour of the ruby is obtained ; and, though the ordinary "strass," or fine lead-glass, is very soft, and therefore soon loses its lustre, it is yet possible to produce a paste consisting of silicate of alumina which is almost as hard as rock crystal. It is an interesting fact that the chemist has frequently suc- ceeded in causing alumina to assume artificially many of the physical characteristics of the native ruby. As far back as 1837 M. Gaudin reproduced the ruby on a small scale by exposing ammonia-alum to the heat of the oxyhydrogen blowpipe, whereby he obtained fused alumina which was readily coloured by the addition of oxide of chromium. A different method AMIS followed by Ebelmen. He dissolved alumina in boric acid at a high temperature, and on the cooling of the mass obtained the alumina in a crystallized form ; while if chromate of ammonium was E'esent the crystals became veritable ruby. MM. Sainte-Claire eville and Caron heated a mixture of fluoride of aluminium, fluoride of chromium, and boric acid, and thus obtained a fluoride of boron, which, being volatile, readily escaped, and left a solid residue of alumina coloured by the chrome. These, however, were only laboratory experiments, and it was reserved for MM. Fre"my and Feil, in 1878, to reproduce the ruby and sapphire on a scale sug- gestive of some commercial importance. By heating a mixture of artificial alumina and red lead in a fireclay crucible, they obtained a vitreous silicate of lead (the silica being derived from the crucible) and crystallized alumina, while the addition of bichromate of potas- sium caused this alumina to assume the coveted tint of the ruby. For a general description of the ruby see E. Junnettaz, Diamant et Pit-rres Precieuses (1881); Kluge, Handbuch der Edelsteinkunde (1860); Schrauf, EJrltteinkuTHle (1R69); Church, Precious Stones (1883); Streeter, Preciout Stontt and Gems (4th ed., 1884). For Indian localities sec Ball's Economic Geology, beiiiR vol. lil. of the Manual of the Geology of India (1881); for Australian localities, Liversidgc's Minerals of New South Wales (2d ed., 1882); for United States rubies, Quart. Jour. Geol. Soc. Lond., v..l. xxx. 1874, p. 303. and American Jour. Science, er. lii. vol. iv. 1872, pp. 109, 175, and Kunz's article in il Resources of the United States, by A. Williams, jun. (1883). For the history of the stone consult King's Natural Hit'., of Precious Stones (1865), and for artificial rubies, Comptet Rtndui, vol. Ixxxv. 1877, p. 1020. (F. W. R.) 