Page:Elementary Principles in Statistical Mechanics (1902).djvu/166

142 that extension-in-phase, if they leave it, the exceptions, i. e., the number which pass out of the extension-in-phase and do not return to it, being less than any assignable fraction of the whole number. In other words, the probability that a system taken at random from the part of a canonical ensemble which is contained within any given extension-in-phase, will pass out of that extension and not return to it, is zero.

A similar theorem may be enunciated with respect to a microcanonical ensemble. Let us consider the fractional part of such an ensemble which lies within any given limits of phase. This fraction we shall denote by $$F$$. It is evidently constant in time since the ensemble is in statistical equilibrium. The systems within the limits will not in general remain the same, but some will pass out in each unit of time while an equal number come in. Some may pass out never to return within the limits. But the number which in any time however long pass out of the limits never to return will not bear any finite ratio to the number within the limits at a given instant. For, if it were otherwise, let $$f$$ denote the fraction representing such ratio for the time $$T$$. Then, in the time $$T$$, the number which pass out never to return will bear the ratio $$fF$$ to the whole number in the ensemble, and in a time exceeding $$T/(fF)$$ the number which pass out of the limits never to return would exceed the total number of systems in the ensemble. The proposition is therefore proved.

This proof will apply to the cases before considered, and may be regarded as more simple than that which was given. It may also be applied to any true case of statistical equilibrium. By a true case of statistical equilibrium is meant such as may be described by giving the general value of the probability that an unspecified system of the ensemble is contained within any given limits of phase.