Page:Elementary Principles in Statistical Mechanics (1902).djvu/139



important case of statistical equilibrium is that in which all systems of the ensemble have the same energy. We may arrive at the notion of a distribution which will satisfy the necessary conditions by the following process. We may suppose that an ensemble is distributed with a uniform density-in-phase between two limiting values of the energy, $$\epsilon'$$ and $$\epsilon''$$, and with density zero outside of those limits. Such an ensemble is evidently in statistical equilibrium according to the criterion in Chapter IV, since the density-in-phase may be regarded as a function of the energy. By diminishing the difference of $$\epsilon'$$ and $$\epsilon''$$, we may diminish the differences of energy in the ensemble. The limit of this process gives us a permanent distribution in which the energy is constant.

We should arrive at the same result, if we should make the density any function of the energy between the limits $$\epsilon'$$ and $$\epsilon''$$, and zero outside of those limits. Thus, the limiting distribution obtained from the part of a canonical ensemble between two limits of energy, when the difference of the limiting energies is indefinitely diminished, is independent of the modulus, being determined entirely by the energy, and is identical with the limiting distribution obtained from a uniform density between limits of energy approaching the same value.

We shall call the limiting distribution at which we arrive by this process microcanonical.

We shall find however, in certain cases, that for certain values of the energy, viz., for those for which $$e^\phi$$ is infinite,