Page:EB1911 - Volume 13.djvu/165

Rh and the accuracy of control and regulation of temperature afforded, render it one of the most convenient agents for the distribution of large quantities of heat in all kinds of manufacturing processes.

36. Spheroidal State.—An interesting contrast to the extreme rapidity with which heat is abstracted by the evaporation of a liquid in contact with a metal plate, is the so-called spheroidal state. A small drop of liquid thrown on a red-hot metal plate assumes a spheroidal form, and continues swimming about for some time, while it slowly evaporates at a temperature somewhat below its boiling-point. The explanation is simply that the liquid itself cannot come in actual contact with the metal plate (especially if the latter is above the critical temperature), but is separated from it by a badly conducting film of vapour, through which, as we have seen, the heat is comparatively slowly transmitted even if the difference of temperature is several hundred degrees. If the metal plate is allowed to cool gradually, the drop remains suspended on its cushion of vapour, until, in the case of water, a temperature of about 200° C. is reached, at which the liquid comes in contact with the plate and boils explosively, reducing the temperature of the plate, if thin, almost instantaneously to 100° C. The temperature of the metal is readily observed by a thermo-electric method, employing a platinum dish with a platinum-rhodium wire soldered with gold to its under side. The absence of contact between the liquid and the dish in the spheroidal state may also be shown by connecting one terminal of a galvanometer to the drop and the other through a battery to the dish, and observing that no current passes until the drop boils.

37. Early Theories of Radiation.—It was at one time supposed that there were three distinct kinds of radiation—thermal, luminous and actinic, combined in the radiation from a luminous source such as the sun or a flame. The first gave rise to heat, the second to light and the third to chemical action. The three kinds were partially separated by a prism, the actinic rays being generally more refracted, and the thermal rays less refracted than the luminous. This conception arose very naturally from the observation that the feebly luminous blue and violet rays produced the greatest photographic effects, which also showed the existence of dark rays beyond the violet, whereas the brilliant yellow and red were practically without action on the photographic plate. A thermometer placed in the blue or violet showed no appreciable rise of temperature, and even in the yellow the effect was hardly discernible. The effect increased rapidly as the light faded towards the extreme red, and reached a maximum beyond the extreme limits of the spectrum (Herschel), showing that the greater part of the thermal radiation was altogether non-luminous. It is now a commonplace that chemical action, colour sensation and heat are merely different effects of one and the same kind of radiation, the particular effect produced in each case depending on the frequency and intensity of the vibration, and on the nature of the substance on which it falls. When radiation is completely absorbed by a black substance, it is converted into heat, the quantity of heat produced being equivalent to the total energy of the radiation absorbed, irrespective of the colour or frequency of the different rays. The actinic or chemical effects, on the other hand, depend essentially on some relation between the period of the vibration and the properties of the substance acted on. The rays producing such effects are generally those which are most strongly absorbed. The spectrum of chlorophyll, the green colouring matter of plants, shows two very strong absorption bands in the red. The red rays of corresponding period are found to be the most active in promoting the growth of the plant. The chemically active rays are not necessarily the shortest. Even photographic plates may be made to respond to the red rays by staining them with pinachrome or some other suitable dye.

The action of light rays on the retina is closely analogous to the action on a photographic plate. The retina, like the plate, is sensitive only to rays within certain restricted limits of frequency. The limits of sensitiveness of each colour sensation are not exactly defined, but vary slightly from one individual to another, especially in cases of partial colour-blindness, and are modified by conditions of fatigue. We are not here concerned with these important physiological and chemical effects of radiation, but rather with the question of the conversion of energy of radiation into heat, and with the laws of emission and absorption of radiation in relation to temperature. We may here also assume the identity of visible and invisible radiations from a heated body in all their physical properties. It has been abundantly proved that the invisible rays, like the visible, (1) are propagated in straight lines in homogeneous media; (2) are reflected and diffused from the surface of bodies according to the same law; (3) travel with the same velocity in free space, but with slightly different velocities in denser media, being subject to the same law of refraction; (4) exhibit all the phenomena of diffraction and interference which are characteristic of wave-motion in general; (5) are capable of polarization and double refraction; (6) exhibit similar effects of selective absorption. These properties are more easily demonstrated in the case of visible rays on account of the great sensitiveness of the eye. But with the aid of the thermopile or other sensitive radiometer, they may be shown to belong equally to all the radiations from a heated body, even such as are thirty to fifty times slower in frequency than the longest visible rays. The same physical properties have also been shown to belong to electromagnetic waves excited by an electric discharge, whatever the frequency, thus including all kinds of aetherial radiation in the same category as light.

38. Theory of Exchanges.—The apparent concentration of cold by a concave mirror, observed by G. B. Porta and rediscovered by M. A. Pictet, led to the enunciation of the theory of exchanges by Pierre Prevost in 1791. Prevost’s leading idea was that all bodies, whether cold or hot, are constantly radiating heat. Heat equilibrium, he says, consists in an equality of exchange. When equilibrium is interfered with, it is re-established by inequalities of exchange. If into a locality at uniform temperature a refracting or reflecting body is introduced, it has no effect in the way of changing the temperature at any point of that locality. A reflecting body, heated or cooled in the interior of such an enclosure, will acquire the surrounding temperature more slowly than would a non-reflector, and will less affect another body placed at a little distance, but will not affect the final equality of temperature. Apparent radiation of cold, as from a block of ice to a thermometer placed near it, is due to the fact that the thermometer being at a higher temperature sends more heat to the ice than it received back from it. Although Prevost does not make the statement in so many words, it is clear that he regards the radiation from a body as depending only on its own nature and temperature, and as independent of the nature and presence of any adjacent body. Heat equilibrium in an enclosure of constant temperature such as is here postulated by Prevost, has often been regarded as a consequence of Carnot’s principle. Since difference of temperature is required for transforming heat into work, no work could be obtained from heat in such a system, and no spontaneous changes of temperature can take place, as any such changes might be utilized for the production of work. This line of reasoning does not appear quite satisfactory, because it is tacitly assumed, in the reasoning by which Carnot’s principle was established, as a result of universal experience, that a number of bodies within the same impervious enclosure, which contains no source of heat, will ultimately acquire the same temperature, and that difference of temperature is required to produce flow of heat. Thus although we may regard the equilibrium in such an enclosure as being due to equal exchanges of heat in all directions, the equal and opposite streams of radiation annul and neutralize each other in such a way that no actual transfer of energy in any direction takes place. The state of the medium is everywhere the same in such an enclosure, but its energy of agitation per unit volume is a function of the temperature, and is such that it would not be in equilibrium with any body at a different temperature.

39. ''”Full” and Selective Radiation. Correspondence of'' Emission and Absorption.—The most obvious difficulties in the