Page:EB1911 - Volume 12.djvu/210

 divided, as in “purple of Cassius,” or when it is precipitated from solutions, the colour is ruby-red, while in very thin leaves it transmits a greenish light. It is nearly as soft as lead and softer than silver. When pure, it is the most malleable of all metals (see ). It is also extremely ductile; a single grain may be drawn into a wire 500 ft. in length, and an ounce of gold covering a silver wire is capable of being extended more than 1300 m. The presence of minute quantities of cadmium, lead, bismuth, antimony, arsenic, tin, tellurium and zinc renders gold brittle, th part of one of the three metals first named being sufficient to produce that quality. Gold can be readily welded cold; the finely divided metal, in the state in which it is precipitated from solution, may be compressed between dies into disks or medals. The specific gravity of gold obtained by precipitation from solution by ferrous sulphate is from 19·55 to 20·72. The specific gravity of cast gold varies from 18·29 to 19·37, and by compression between dies the specific gravity may be raised from 19·37 to 19·41; by annealing, however, the previous density is to some extent recovered, as it is then found to be 19·40. The melting-point has been variously given, the early values ranging from 1425° C. to 1035° C. Using improved methods, C. T. Heycock and F. H. Neville determined it to be 1061·7° C.; Daniel Berthelot gives 1064° C., while Jaquerod and Perrot give 1066·1–1067·4° C. At still higher temperatures it volatilizes, forming a reddish vapour. Macquer and Lavoisier showed that when gold is strongly heated, fumes arise which gild a piece of silver held in them. Its volatility has also been studied by L. Eisner, and, in the presence of other metals, by Napier and others. The volatility is barely appreciable at 1075°; at 1250° it is four times as much as at 1100°. Copper and zinc increase the volatility far more than lead, while the greatest volatility is induced, according to T. Kirke Rose, by tellurium. It has also been shown that gold volatilizes when a gold-amalgam is distilled. Gold is dissipated by sending a powerful charge of electricity through it when in the form of leaf or thin wire. The electric conductivity is given by A. Matthiessen as 73 at 0° C., pure silver being 100; the value of this coefficient depends greatly on the purity of the metal, the presence of a few thousandths of silver lowering it by 10%. Its conductivity for heat has been variously given as 103 (C. M. Despretz), 98 (F. Crace-Calvert and R. Johnson), and 60 (G. H. Wiedemann and R. Franz), pure silver being 100. Its specific heat is between 0·0298 (Dulong and Petit) and 0·03244 (Regnault). Its coefficient of expansion for each degree between 0° and 100° C. is 0·000014661, or for gold which has been annealed 0·000015136 (Laplace and Lavoisier). The spark spectrum of gold has been mapped by A. Kirchhoff, R. Thalén, Sir William Huggins and H. Krüss; the brightest lines are 6277, 5960, 5955 and 5836 in the orange and yellow, and 5230 and 4792 in the green and blue.

Chemical Properties.—Gold is permanent in both dry and moist air at ordinary or high temperatures. It is insoluble in hydrochloric, nitric and sulphuric acids, but dissolves in aqua regia—a mixture of hydrochloric and nitric acids—and when very finely divided in a heated mixture of strong sulphuric acid and a little nitric acid; dilution with water, however, precipitates the metal as a violet or brown powder from this solution. The metal is soluble in solutions of chlorine, bromine, thiosulphates and cyanides; and also in solutions which generate chlorine, such as mixtures of hydrochloric acid with nitric acid, chromic acid, antimonious acid, peroxides and nitrates, and of nitric acid with a chloride. Gold is also attacked when strong sulphuric acid is submitted to electrolysis with a gold positive pole. W. Skey showed that in substances which contain small quantities of gold the precious metal may be removed by the solvent action of iodine or bromine in water. Filter paper soaked with the clear, solution is burnt, and the presence of gold is indicated by the purple colour of the ash. In solution minute quantities of gold may be detected by the formation of “purple of Cassius,” a bluish-purple precipitate thrown down by a mixture of ferric and stannous chlorides.

The atomic weight of gold was first determined with accuracy by Berzelius, who deduced the value 195·7 (H＝1) from the amount of mercury necessary to precipitate it from the chloride, and 195·2 from the ratio between gold and potassium chloride in potassium aurichloride, KAuCl4. Later determinations were made by Sir T. E. Thorpe and A. P. Laurie, Krüss and J. W. Mallet. Thorpe and Laurie converted potassium auribromide into a mixture of metallic gold and potassium bromide by careful heating. The relation of the gold to the potassium bromide, as well as the amounts of silver and silver bromide which are equivalent to the potassium bromide, were determined. The mean value thus adduced was 195·86. Krüss worked with the same salt, and obtained the value 195·65; while Mallet, by analyses of gold chloride and bromide, and potassium auribromide, obtained the value 195·77.

Occlusion of Gas by Gold.—T. Graham showed that gold is capable of occluding by volume 0·48% of hydrogen, 0·20% of nitrogen, 0·29% of carbon monoxide, and 0·16% of carbon dioxide. Varrentrapp pointed out that “cornets” from the assay of gold may retain gas if they are not strongly heated.

Occurrence and Distribution.—Gold is found in nature chiefly in the metallic state, i.e. as “native gold,” and less frequently in combination with tellurium, lead and silver. These are the only certain examples of natural combinations of the metal, the minute, though economically valuable, quantity often found in pyrites and other sulphides being probably only present in mechanical suspension. The native metal crystallizes in the cubic system, the octahedron being the commonest form, but other and complex combinations have been observed. Owing to the softness of the metal, large crystals are rarely well defined, the points being commonly rounded. In the irregular crystalline aggregates branching and moss-like forms are most common, and in Transylvania thin plates or sheets with diagonal structures are found. More characteristic, however, than the crystallized are the irregular forms, which, when large, are known as “nuggets” or “pepites,” and when in pieces below to  oz. weight as gold dust, the larger sizes being distinguished as coarse or nuggety gold, and the smaller as gold dust proper. Except in the larger nuggets, which may be more or less angular, or at times even masses of crystals, with or without associated quartz or other rock, gold is generally found bean-shaped or in some other flattened form, the smallest particles being scales of scarcely appreciable thickness, which, from their small bulk as compared with their surface, subside very slowly when suspended in water, and are therefore readily carried away by a rapid current. These form the “float gold” of the miner. The physical properties of native gold are generally similar to that of the melted metal.

Of the minerals containing gold the most important are sylvanite or graphic tellurium (Ag, Au) Te2, with 24 to 26%; calaverite, AuTe2, with 42%; nagyagite or foliate tellurium (Pb, Au)16 Sb3(S, Te)24, with 5 to 9% of gold; petzite, (Ag, Au)2Te, and white tellurium. These are confined to a few localities, the oldest and best known being those of Nagyag and Offenbanya in Transylvania; they have also been found at Red Cloud, Colorado, in Calaveras county, California, and at Perth and Boulder, West Australia. The minerals of the second class, usually spoken of as “auriferous,” are comparatively numerous. Prominent among these are galena and iron pyrites, the former being almost invariably gold-bearing. Iron pyrites, however, is of greater practical importance, being in some districts exceedingly rich, and, next to the native metal, is the most prolific source of gold. Magnetic pyrites, copper pyrites, zinc blende and arsenical pyrites are other and less important examples, the last constituting the gold ore formerly worked in Silesia. A native gold amalgam is found as a rarity in California, and bismuth from South America is sometimes rich in gold. Native arsenic and antimony are also very frequently found to contain gold and silver.

The association and distribution of gold may be considered under two different heads, namely, as it occurs in mineral veins—“reef gold,” and in alluvial or other superficial deposits which are derived from the waste of the former—“alluvial gold.” Four distinct types of reef gold deposits may be distinguished: (1) Gold may occur disseminated through metalliferous veins, generally with sulphides and more particularly with pyrites. These deposits seem to be the primary sources of native gold. (2) More common are the auriferous quartz-reefs—veins or masses of quartz containing gold in flakes visible to the naked eye, or so finely divided as to be invisible. (3) The “banket” formation, which characterizes the goldfields of South Africa, consists of a quartzite conglomerate throughout which gold is very finely disseminated. (4) The siliceous sinter at