Page:EB1911 - Volume 11.djvu/579

 has not been detected in the sapphire. Probably the most common mineral pigments are compounds of iron, manganese, copper and chromium. If the colour of the stone be discharged by heat, an organic pigment is presumably present. Some ornamental stones change their colour, or even lose it, on exposure to sunlight and air: such is the case with rose-quartz, chrysoprase and certain kinds of topaz and turquoise. Exposure to heat alters the colour of some stones so readily that the change is taken advantage of commercially; thus, sherry-yellow topaz may be rendered pink, smoky and amethystine quartz may become yellow, and coloured zircons may be decolorized, so as to resemble diamonds.

The colours of some gem-stones are greatly affected by radioactivity, and Prof. F. Bordas has found this to be particularly the case with sapphire. From his experiments he believes that yellow corundum, or oriental topaz, may have been formed from blue corundum under the influence of radioactive substances present in the soil in which the sapphire was embedded. Different shades of colour may be presented by different stones of the same species; and it was formerly the custom of lapidaries to regard the darker stones as masculine and the paler as feminine, a full blue sapphire, for instance, being called a “male sapphire” and a delicate blue stone a “female sapphire.” It is notable that some stones appear to change colour by candle-light and by most other artificial means of illumination; some amethysts thus become inky, and certain sapphires acquire a murky tint, whilst others become amethystine. For an example of a remarkable change of this character, see.

As the optical properties of minerals are fully explained under , little need be said here on this subject. The brilliancy of a cut stone depends on the amount of light reflected from its faces; and in the form known as the “brilliant” the gem is so cut that much

of the incident light, after entering the stone and suffering refraction, is totally reflected from the facets at the back. The amount of light which is thus returned to the eye of the observer will be greater as the angle of total reflection, or critical angle, is smaller, but this angle will be small if the refractive power of the stone is great, so that the brilliancy directly depends on the refractivity. The diamond has the highest refractive index of any gem-stone (2·42). Jargoon, or zircon, has also a high index (mean 1·95), and sphene, which is occasionally cut as a gem, is likewise very notable in this respect. The index of refraction generally bears a relation to the specific gravity of the stone, the heaviest gems having the highest indices, though a few minerals offer exceptions. The refractive index, which is thus a very important character in the scientific discrimination of gem-stones, may be conveniently determined, within certain limits, by means of the refractometer devised by Dr G.F. Herbert Smith. This instrument is an improved form of the total reflectometer, in which the refractive power of a given substance is determined by the method of total reflection. It may be used for indices ranging from 1·300 to 1·775, and may be applied to faceted stones without removal from their settings.

The play of prismatic colours exhibited by a cut stone, often known as its “fire,” is due to the decomposition of the white light which enters the stone, and is returned, by internal reflection, after resolution in to its coloured components. This decomposition depends on the dispersive power

of the substance. The exceptional beauty of the fiery flashes in the diamond is due to its high dispersion, in other words, to the difference between the refractive indices for the red rays and the violet rays at the extremities of the spectrum. The peculiar lustre exhibited by the diamond is called adamantine, and is shared to some extent by certain other stones which have a high refractive index and high dispersion, such as zircon.

The use of the spectroscope may be valuable in discriminating between certain precious stones. It was shown by Sir A. H. Church that almandine garnet and zircon when simply viewed through this instrument give, under proper conditions, characteristic absorption spectra, due to

the light reflected from the stone having penetrated to some extent into the substance of the mineral and suffered absorption. It is sometimes useful to examine the behaviour of a stone under the action of the Röntgen rays.

A very useful means of discriminating between certain stones is found in their dichroism, or, to use a more general term, pleochroism. Neither amorphous minerals, like opal, nor minerals crystallizing in the cubic system, like spinel and garnet, possess this property; but coloured

minerals which are doubly refracting may show different colours, when properly examined, in different directions. Occasionally this is so marked as to be detected by the naked eye, as in iolite or dichroite, but usually the stone needs to be examined with such an instrument as Haidinger’s dichroscope (see ). It must be remembered that in the direction of an optic axis the two images will be of the same colour in all positions of the instrument, and it is therefore necessary before reaching a definite conclusion to turn the stone about and examine it in various directions. The use of the dichroscope is so simple that it can be applied by any one to the examination of a cut stone, but there are other means of determining the nature of a stone by its optical properties available to the mineralogist and more suitably discussed under.

In chemical composition the gem-stones present great variety. Diamond is composed of only a single element; ruby, sapphire and the quartz-group are oxides; spinel and chrysoberyl may be regarded as aluminates; turquoise and beryllonite are phosphates; and a great number of

ornamental stones are silicates of greater or less complexity, such as emerald, topaz, chrysolite, garnet, zircon, tourmaline, kunzite, sphene and benitoite. In the examination of a cut stone chemical tests are not available, since they usually involve the partial destruction of the mineral. The artificial production of certain gems by chemical processes which yield products identical in composition and physical properties with the natural stones, is described in the article.

Doublets and triplets are composite stone, sometimes prepared for fraudulent purposes. In a doublet a slab of real gem-stone covers the face of a paste, whilst in a triplet the paste is both faced and backed by a slice of genuine stone. By the action of a suitable solvent, such as chloroform or in some cases even hot water, the cement uniting the pieces gives way and the compound character of the structure is detected.

Before the chemical composition of gem-stones was understood, their classification remained vague and unscientific. As the ancients depended almost entirely on the eye, the colour of the stone naturally became the chief factor in classification. A variety of stones agreeing roughly in colour would be grouped together under a common name, widely as they might differ in other respects. Thus the emerald, the peridot, green fluorspar, malachite, and certain kinds of quartz and jade seem to have been united under the general name of  whilst the ruby, red spinel and garnet were probably grouped together as carbunculus. In this way minerals radically different were associated on the ground of what is generally a superficial and accidental character, and rarely of any classificatory value. On the other hand, a grouping based only on colour led to several names being in some cases applied to the same mineral species. Thus the ruby and sapphire are essentially identical in chemical composition and in all physical characters, save colour.

Descriptions of precious stones by ancient writers generally are too vague for exact diagnosis. The principal classical authorities are Theophrastus and the elder Pliny. Stones were formerly held in esteem not only for their beauty and rarity but for the medicinal and magical powers with

which they were reputed to be endowed. Up to comparatively recent years the toadstone, for example, was worn not for beauty but for sake of occult virtue; and even at the present day certain stones, like jade, are valued for a similar reason. Prof. W. Ridgeway has suggested that jewelry took its origin not, as often supposed, in an innate love of personal decoration, but rather in the belief that the objects used possessed magical virtue. Small stones peculiar in colour or shape, especially those with natural perforations, are usually valued by uncivilized peoples