Page:EB1911 - Volume 08.djvu/777

 properties, others are sulphonic acid derivatives of Alizarin Colours, suitable for wool but not for cotton.

Red.—Alizarin, anthrapurpurin, flavopurpurin, purpurin, alizarin Bordeaux, alizarin garnet R, alizarin maroon, alizarin S, cloth red, diamine fast red, anthracene red, chrome red, chrome Bordeaux, salicine red, erio chrome red, emin red, milling red.

Orange and Yellow.—Alizarin orange, alizarin orange G, alizarin yellow paste, alizarin yellow A, alizarin yellow C, anthracene yellow, galloflavin, alizarin yellow GG, alizarin yellow R, diamond flavin G, chrome yellow D, Crumpsall yellow, fast yellow, diamond yellow, benzo orange R, cloth orange, carbazol yellow, chrysamine, milling orange.

Green.—Coeruleïn, coeruleïn S, alizarin green S, fast green (Fe), naphthol green (Fe), Dioxin (Fe), Gambine (Fe), azo green, gallanil green, alizarin green G and B, acid alizarin green, alizarin cyanine green, alizarin viridine, diamond green, chrome green, Domingo green.

Blue.—Alizarin blue, alizarin blue S, alizarin cyanine, anthracene blue, brilliant alizarin blue, alizarin indigo blue S, gallanilic indigo, acid alizarin blue, brilliant alizarin cyanine, alizarin grisole, alizarin sky blue, alizarin saphirole, gallanilide blue, delphine blue, gallamine blue, celestine blue, chrome blue, gallazine A, phenocyanine, coreïne.

Purple and Violet.—Galleïn, alizarin heliotrope, anthraquinone violet, chrome prime, gallocyanine, chrome violet, anthracene chrome violet.

Brown.—Anthracene brown, chromogen, cloth brown, diamond brown, alizarin brown, fast brown, alizarin acid brown, chrome brown, palatine chrome brown, erio chrome brown.

Black.—Alizarin black, diamond black, alizarin blue black, alizarin cyanine black, alizarin fast grey, chromotrope, chrome black, erio chrome black, anthracite black, acid alizarin black, anthracene chrome black.

A brief description of the application of a few of the more important of the above colouring matters will suffice.

Alizarin, Anthrapurpurin and Flavopurpurin give somewhat similar shades with the different mordants, namely, brown with chromium, red with aluminium, orange with tin, and purple with iron.

In wool-dyeing they are applied along with other Mordant Colours on chromium mordant for the production of a large variety of compound shades, browns, drabs, greys, &c., the presence of acetic acid in the dyebath being advantageous. When alum and tartar mordant is employed, for the production of reds, it is necessary to add a small amount (4%) of calcium acetate to the dyebath, in order to neutralize the strong acidity of the mordanted wool, and to furnish the calcium of the colour-lake fixed upon the fibre, which is regarded as an aluminium-calcium compound of the colouring matter.

In cotton-dyeing the above colouring matters are chiefly used for the production of so-called Turkey-red, a colour remarkable for its brilliancy and its fastness to light and soap. These properties are due to the preparation of the cotton with oil, in addition to the ordinary mordanting and dyeing, whereby there is fixed on the fibre a permanent and stable lake, in which aluminium and calcium are combined with alizarin and some form of fatty oxy-acid. In the older processes employed, the preparation of the cotton with oil was effected by passing the material several times through emulsions of olive oil and potassium carbonate solution; at a later date, and even now in the case of cloth, the cotton is first impregnated with hot oil (Steiner's process), then passed through solutions of alkali carbonate. After the preparation with oil or oil-emulsions, the cotton is “stoved,” i.e. heated for several hours in special chambers or stoves to a temperature of about 70° C., during which operation the oil is decomposed and oxidized and becomes indelibly attached to the fibre. The oil-prepared cotton is steeped in cold solutions of basic aluminium sulphate or acetate, washed, dyed with alizarin, and finally boiled for several hours with soap solution under pressure in order to brighten the colour. In the more recent and much more expeditious “sulphated-oil process,” castor oil is employed instead of olive oil, and before use it is submitted to a treatment with sulphuric acid, the sulphated oil thus obtained being finally more or less neutralized with alkali. The cotton is impregnated with this sulphated-oil solution, dried, mordanted with aluminium acetate, dyed, dried, steamed and soaped. The operation of steaming plays an important part in brightening and fixing the colour-lake on the fibre. In these and all other Turkey-red processes, the oil, probably in the form of a fatty oxy-acid, acts as a fixing agent for the aluminium and enters into the composition of the red lake, imparting to it both brilliancy and permanency.

Alizarin S is a sulphonic acid derivative of alizarin, and since it is much more soluble, it readily yields level colours. Silk is dyed in a similar manner to wool, the fibre being mordanted by the ordinary methods and then dyed in a separate bath.

Diamine Fast Red is applied to cotton as a Direct Colour, with the addition of soda or soap to the dyebath. By treating the dyed colour with a solution of fluoride of chromium, its fastness to washing is materially increased. Wool is dyed in a similar manner, sodium sulphate being added to the dyebath, and the dyed colour treated with fluoride of chromium or bichromate of potash. On wool, the colour is so extremely fast to light and to milling that it may well serve as a substitute for alizarin.

Alizarin Orange is employed in the same manner as alizarin. In wool-dyeing it is usually applied on chromium mordant for browns and a variety of compound shades in combination with other Alizarin Colours and dyewood extracts, less frequently on aluminium mordant.

Galloflavin is used in wool and silk dyeing on chromium mordant as a substitute for fustic and other yellow dyewoods, to furnish the yellow part of compound shades.

The alizarin yellows, R and GG, anthracene yellow, diamond flavine, chrome yellow, diamond yellow, carbazol yellow, chrysamine, &c., are Direct Colours with mordant-dyeing properties. They also serve as substitutes for fustic in wool or silk dyeing, and are dyed either on a chromium mordant, or first in an acid bath and afterwards saddened with bichromate of potash.

Coeruleïn is employed in dyeing wool, silk or cotton with aluminium or chromium mordants, either as a self-colour or for compound shades. With aluminium mordant the colour is a moderately bright green, more particularly on silk; with chromium mordant, an olive-green. Coeruleïn S is the more soluble bisulphite compound of the ordinary coeruleïn. It is applied in the same manner, care being taken, however, to dye for some time (one hour) at a temperature not exceeding 60° C. until the bath is nearly exhausted, and then only raising the temperature to the boiling point. Without this precaution coeruleïn S is decomposed, and the ordinary insoluble coeruleïn is precipitated. The colours obtained are very fast to light.

Fast Green, Dioxine and Gambine are chiefly of use in calico-printing and in wool-dyeing. With iron mordant they yield olive-greens, which on wool are extremely fast to light. Cotton is impregnated with ferrous acetate, dried, aged and fixed with silicate of soda, then dyed in a neutral bath. Wool is mordanted with ferrous sulphate and tartar (3% of each) and dyed in a neutral bath.

Acid Alizarin Green, Alizarin Cyanine Green and Diamond Green all dye wool direct in a bath acidified with acetic or sulphuric acid, and the dyed colour may be afterwards fixed or saddened with bichromate of potash, or they may be dyed on chromium-mordanted wool. The first method is very useful for pale shades, since the colours are very level or regular.

Alizarin Blue is a dark blue dyestuff which, owing to the fastness of the colours it yields, has for many years been regarded as a worthy substitute for indigo in wool-dyeing. It is applied in the same manner as alizarin, the chromium mordant being alone employed. Alizarin blue S is the soluble sodium bisulphite compound of alizarin blue; it corresponds, therefore, to the above-mentioned coeruleïn S, and in its application the same precautions as to the temperature of the dyebath are necessary. The fastness of the dyed colours to light, milling and acid satisfy the highest requirements.

Alizarin Cyanine, Anthracene Blue and Brilliant Alizarin Blue were discovered later than the above-mentioned alizarin blues, and, owing to their greater solubility and other advantages, they have largely replaced them as substitutes for indigo. They are dyed on chromium-mordanted wool, silk or cotton, and yield dark purplish or greenish blues, according to the particular brand employed. The fastness of the dyed colours to light, and general durability, are very satisfactory, but in fastness to milling and acids they are to some extent inferior to alizarin blue.

Celestine Blue and Chrome Blue dye purplish blue and bright blue respectively, and are dyed in the ordinary way upon a chromium mordant. The colours they yield are inferior to the Alizarin Colours in fastness to light, but on account of their clear shades they are often used for brightening other colours.

Brilliant Alizarin Cyanine, Alizarin Viridine and Alizarin Saphirole are true Alizarin Colours, and possess the same fastness to light as other colours of this class. Unlike most of the Alizarin Colours, they are capable of dyeing wool satisfactorily without the aid of a metallic mordant—namely, with the addition of sulphuric acid to the dyebath, in the same manner as the Acid Colours. If necessary, the dyed colours may be treated with bichromate of potash. The colours thus produced are very fast to light and very level, hence these dyestuffs are valuable in the production of the most delicate compound shades, such as drabs, slates, greys, &c., which are desired to be fast to light. Alizarin saphirole dyes clear blue, the colour produced being much more brilliant even than those of brilliant alizarin cyanine.

Galleïn, Gallocyanine, and especially Chrome Violet, dye somewhat bright purple shades, and are hence frequently employed for brightening other colours, but they are only moderately fast to light. They are applied in the usual manner on a chromium mordant.

Anthracene Brown is largely employed in the production of compound shades. It dyes a dark, somewhat reddish, brown on chromium mordant, the colour being very even and extremely fast to light.

Alizarin Black is dyed on chromium mordant in the same manner as alizarin, and is used as a self-colour or in combination with other Alizarin Colours.

Diamond Black is very useful for dyeing good blacks on wool, fast to light and acids. The wool is first dyed with the addition of acetic and finally sulphuric acid. When the dyebath is exhausted,