Page:EB1911 - Volume 07.djvu/610

Rh bisects the acute angle being called the “acute bisectrix” or “first mean line,” and the other the “obtuse bisectrix” or “second mean line.” When the acute bisectrix coincides with the greatest axis OC of the indicatrix, i.e. the vibration-direction corresponding with the refractive index (as in figs. 98 and 99), the crystal is described as being optically positive; and when the acute bisectrix coincides with OA, the vibration-direction for the index, the crystal is negative. The distinction between positive and negative biaxial crystals thus depends on the relative magnitude of the three principal indices of refraction; in positive crystals is nearer to  than to, whilst in negative crystals the reverse is the case. Thus in topaz, which is optically positive, the refractive indices for sodium light are = 1.6120, = 1.6150, = 1.6224; and for orthoclase which is optically negative, = 1.5190,  = 1.5237,  = 1.5260. The difference &minus; represents the strength of the double refraction.

Since the refractive indices vary both with the colour of the light and with the temperature, there will be for each colour and temperature slight differences in the form of both the indicatrix and the ray-surface: consequently there will be variations in the positions of the optic axes and in the size of the optic axial angle. This phenomenon is known as the “dispersion of the optic axes.” When the axial angle is greater for red light than for blue the character of the dispersion is expressed by &gt; , and when less by &lt;. In some crystals, e.g. brookite, the optic axes for red light and for blue light may be, at certain temperatures, in planes at right angles.

The type of interference figure exhibited by a biaxial crystal in convergent polarized light between crossed nicols is represented in figs. 100 and 101. The crystal must be viewed along the acute bisectrix, and for this purpose it is often necessary to cut a plate from the crystal perpendicular to this direction: sometimes, however, as in mica and topaz, a cleavage flake will be perpendicular to the acute bisectrix. When seen in white light, there are around each optic axis a series of brilliantly coloured ovals, which at the centre join to form an 8-shaped loop, whilst further from the centre the curvature of the rings is approximately that of lemniscates. In the position shown in fig. 100 the vibration-directions in the crystal are parallel to those of the nicols, and the figure is intersected by two black bands or “brushes” forming a cross. When, however, the crystal is rotated with the stage of the microscope the cross breaks up into the two branches of a hyperbola, and when the vibration-directions of the crystal are inclined at 45° to those of the nicols the figure is that shown in fig. 101. The points of emergence of the optic axes are at the middle of the hyperbolic brushes when the crystal is in the diagonal position: the size of the optic axial angle can therefore be directly measured with considerable accuracy.

In orthorhombic crystals the three principal vibration-directions coincide with the three crystallographic axes, and have therefore fixed positions in the crystal, which are the same for light of all colours and at all temperatures. The optical orientation of an orthorhombic crystal is completely defined by stating to which crystallographic planes the optic axial plane and the acute bisectrix are respectively parallel and perpendicular. Examined in parallel light between crossed nicols, such a crystal extinguishes parallel to the crystallographic axes, which are often parallel to the edges of a face or section; there is thus usually “straight extinction.” The interference figure seen in convergent polarized light is symmetrical about two lines at right angles.

In monoclinic crystals only one vibration-direction has a fixed position within the crystal, being parallel to the ortho-axis (i.e. perpendicular to the plane of symmetry or the plane (010)). The other two vibration-directions lie in the plane (010), but they may vary in position for light of different colours and at different temperatures. In addition to dispersion of the optic axes there may thus, in crystals of this system, be also “dispersion of the bisectrices.” The latter may be of one or other of three kinds, according to which of the three vibration-directions coincides with the ortho-axis of the crystal. When the acute bisectrix is fixed in position, the optic axial planes for different colours may be crossed, and the interference figure will then be symmetrical with respect to a point only (“crossed dispersion”). When the obtuse bisectrix is fixed, the axial planes may be inclined to one another, and the interference figure is symmetrical only about a line which is perpendicular to the axial planes (“horizontal dispersion”). Finally, when the vibration-direction corresponding to the refractive index, or the “third mean line,” has a fixed position, the optic axial plane lies in the plane (010), but the acute bisectrix may vary in position in this plane; the interference figure will then be symmetrical only about a line joining the optic axes (“inclined dispersion”). Examples of substances exhibiting these three kinds of dispersion are borax, orthoclase and gypsum respectively. In orthoclase and gypsum, however, the optic axial angle gradually diminishes as the crystals are heated, and after passing through a uniaxial position they open out in a plane at right angles to the one they previously occupied; the character of the dispersion thus becomes reversed in the two examples quoted. When examined in parallel light between crossed nicols monoclinic crystals will give straight extinction only in faces and sections which are perpendicular to the plane of symmetry (or the plane (010)); in all other faces and sections the extinction-directions will be inclined to the edges of the crystal. The angles between these directions and edges are readily measured, and, being dependent on the optical orientation of the crystal, they are often characteristic constants of the substance (see, e.g., ).

In anorthic crystals there is no relation between the optical and crystallographic directions, and the exact determination of the optical orientation is often a matter of considerable difficulty. The character of the dispersion of the bisectrices and optic axes is still more complex than in monoclinic crystals, and the interference figures are devoid of symmetry.

Absorption of Light in Crystals: Pleochroism.—In crystals other than those of the cubic system, rays of light with different vibration-directions will, as a rule, be differently absorbed; and the polarized rays on emerging from the crystal may be of different intensities and (if the observation be made in white light and the crystal is coloured) differently coloured. Thus, in tourmaline the ordinary ray, which vibrates perpendicular to the principal axis, is almost completely absorbed, whilst the extraordinary ray is allowed to pass through the crystal. A plate of tourmaline cut parallel to the principal axis may therefore be used for producing a beam of polarized light, and two such plates placed in crossed position form the polarizer or analyser of “tourmaline tongs,” with the aid of which the interference figures of crystals may be simply shown. Uniaxial (tetragonal and hexagonal) crystals when showing perceptible differences in colour for the ordinary and extraordinary rays are said to be “dichroic.” In biaxial (orthorhombic, monoclinic and anorthic) crystals, rays vibrating along each of the three principal vibration-directions may be differently absorbed, and, in coloured crystals, differently coloured; such crystals are therefore said to be “trichroic” or in general “pleochroic” (from , more, and  , colour). The directions of maximum absorption in biaxial crystals have, however, no necessary relation with the axes of the indicatrix, unless these have fixed crystallographic directions, as in the orthorhombic system and the ortho-axis in the monoclinic. In epidote it has been shown that the two directions