Page:EB1911 - Volume 07.djvu/605

Rh quartets and other complex groupings. When often repeated on the same plane, the twinning is said to be “polysynthetic,” and gives rise to a laminated structure in the crystal. Sometimes such a crystal (e.g. of corundum or pyroxene) may be readily broken in this direction, which is thus a “plane of parting,” often closely resembling a true cleavage in character. In calcite and some other substances this lamellar twinning may be produced artificially by pressure (see below, Sect. II. (a), Glide-plane).

Another curious result of twinning is the production of forms which apparently display a higher degree of symmetry than that actually possessed by the substance. Twins of this kind are known as “mimetic-twins or pseudo-symmetric twins.” Two hemihedral or hemimorphic crystals (e.g. of diamond or of hemimorphite) are often united in twinned position to produce a group with apparently the same degree of symmetry as the holosymmetric class of the same system. Or again, a substance crystallizing in, say, the orthorhombic system (e.g. aragonite) may, by twinning, give rise to pseudo-hexagonal forms: and pseudo-cubic forms often result by the complex twinning of crystals (e.g. stannite, phillipsite, &c.) belonging to other systems. Many of the so-called “optical anomalies” of crystals may be explained by this pseudo-symmetric twinning.

(h) Irregularities of Growth of Crystals; Character of Faces.

Only rarely do actual crystals present the symmetrical appearance shown in the figures given above, in which similar faces are all represented as of equal size. It frequently happens that the crystal is so placed with respect to the liquid in which it grows that there will be a more rapid deposition of material on one part than on another; for instance, if the crystal be attached to some other solid it cannot grow in that direction. Only when a crystal is freely suspended in the mother-liquid and material for growth is supplied at the same rate on all sides does an equably developed form result.

Two misshapen or distorted octahedra are represented in figs. 85 and 86; the former is elongated in the direction of one of the edges of the octahedron, and the latter is flattened parallel to one pair of faces. It will be noticed in these figures that the edges in which the faces intersect have the same directions as before, though here there are additional edges not present in fig. 3. The angles (70° 32′ or 109° 28′) between the faces also remain the same; and the faces have the same inclinations to the axes and planes of symmetry as in the equably developed form. Although from a geometrical point of view these figures are no longer symmetrical with respect to the axes and planes of symmetry, yet crystallographically they are just as symmetrical as the ideally developed form, and, however much their irregularity of development, they still are regular (cubic) octahedra of crystallography. A remarkable case of irregular development is presented by the mineral cuprite, which is often found as well-developed octahedra; but in the variety known as chalcotrichite it occurs as a matted aggregate of delicate hairs, each of which is an individual crystal enormously elongated in the direction of an edge or diagonal of the cube.

The symmetry of actual crystals is sometimes so obscured by irregularities of growth that it can only be determined by measurement of the angles. An extreme case, where several of the planes have not been developed at all, is illustrated in fig. 87, which shows the actual shape of a crystal of zircon from Ceylon; the ideally developed form (fig. 88) is placed at the side for comparison, and the parallelism of the edges between corresponding faces will be noticed. This crystal is a combination of five simple forms, viz. two tetragonal prisms (a and m,) two tetragonal bipyramids (e and p), and one ditetragonal bipyramid (x, with 16 faces).

The actual form, or “habit,” of crystals may vary widely in different crystals of the same substance, these differences depending largely on the conditions under which the growth has taken place. The material may have crystallized from a fused mass or from a solution; and in the latter case the solvent may be of different kinds and contain other substances in solution, or the temperature may vary. (q.v.) affords a good example of a substance crystallizing in widely different habits, but all crystals are referable to the same type of symmetry and may be reduced to the same fundamental form.

When crystals are aggregated together, and so interfere with each other’s growth, special structures and external shapes often result, which are sometimes characteristic of certain substances, especially amongst minerals.

Incipient crystals, the development of which has been arrested owing to unfavourable conditions of growth, are known as (q.v.). They are met with in imperfectly crystallized substances and in glassy rocks (obsidian and pitchstone), or may be obtained artificially from a solution of sulphur in carbon disulphide rendered viscous by the addition of Canada-balsam. To the various forms H. Vogelsang gave, in 1875, the names “globulites,” “margarites” (from , a pearl), “longulites,” &c. At a more advanced stage of growth these bodies react on polarized light, thus possessing the internal structure of true crystals; they are then called “microlites.” These have the form of minute rods, needles or hairs, and are aggregated into feathery and spherulitic forms or skeletal crystals. They are common constituents of microcrystalline igneous rocks, and often occur as inclusions in larger crystals of other substances.

Inclusions of foreign matter, accidentally caught up during growth, are frequently present in crystals. Inclusions of other minerals are specially frequent and conspicuous in crystals of quartz, and crystals of calcite may contain as much as 60% of included sand. Cavities, either with rounded boundaries or with the same shape (“negative crystals”) as the surrounding crystal, are often to be seen; they may be empty or enclose a liquid with a movable bubble of gas.

The faces of crystals are rarely perfectly plane and smooth, but are usually striated, studded with small angular elevations, pitted or cavernous, and sometimes curved or twisted. These irregularities, however, conform with the symmetry of the crystal, and much may be learnt by their study. The parallel grooves or furrows, called “striae,” are the result of oscillatory combination between adjacent faces, narrow strips of first one face and then another being alternately developed. Sometimes