Page:EB1911 - Volume 07.djvu/594

Rh A regular octahedron and a cube are thus each symmetrical with respect to the following elements of symmetry: a centre of symmetry, thirteen axes of symmetry (of three kinds), and nine planes of symmetry (of two kinds). This degree of symmetry, which is the type corresponding to one of the classes of the cubic system, is the highest possible in crystals. As will be pointed out below, it is possible, however, for both the octahedron and the cube to be associated with fewer elements of symmetry than those just enumerated.

(b) Simple Forms and Combinations of Forms.

A single face a1a2a3 (figs. 3 and 4) may be repeated by certain of the elements of symmetry to give the whole eight faces of the octahedron. Thus, by rotation about the vertical tetrad axis a3ā3 the four upper faces are obtained; and by rotation of these about one or other of the horizontal tetrad axes the eight faces are derived. Or again, the same repetition of the faces may be arrived at by reflection across the three cubic planes of symmetry. (By reflection across the six dodecahedral planes of symmetry a tetrahedron only would result, but if this is associated with a centre of symmetry we obtain the octahedron.) Such a set of similar faces, obtained by symmetrical repetition, constitutes a "simple form." An octahedron thus consists of eight similar faces, and a cube is bounded by six faces all of which have the same surface characters, and parallel to each of which all the properties of the crystal are identical.

Examples of simple forms amongst crystallized substances are octahedra of alum and spinel and cubes of salt and fluorspar. More usually, however, two or more forms are present on a crystal, and we then have a combination of forms, or simply a "combination." Figs. 6, 7 and 8 represent combinations of the octahedron and the cube; in the first the faces of the cube predominate, and in the third those of the octahedron; fig. 7 with the two forms equally developed is called a cubo-octahedron. Each of these combined forms has all the elements of symmetry proper to the simple forms.

The simple forms, though referable to the same type of symmetry and axes of reference, are quite independent, and cannot be derived one from the other by symmetrical repetition, but, after the manner of Romé de l'Isle, they may be derived by replacing edges or corners by a face equally inclined to the faces forming the edges or corners; this is known as "truncation" (Lat. truncare, to cut off). Thus in fig. 6 the corners of the cube are symmetrically replaced or truncated by the faces of the octahedron, and in fig. 8 those of the octahedron are truncated by the cube.

(c) Law of Rational Intercepts.

For axes of reference, OX, OY, OZ (fig. 9), take any three edges formed by the intersection of three faces of a crystal. These axes are called the crystallographic axes, and the planes in which they lie the axial planes. A fourth face on the crystal intersecting these three axes in the points A, B, C is taken as the parametral plane, and the lengths OA: OB: OC are the parameters of the crystal. Any other face on the crystal may be referred to these axes and parameters by the ratio of the intercepts

Thus for a face parallel to the plane A Be the intercepts are in the ratio OA: OB: Oe, or

and for a plane fg C  they are Of: Og: O C  or

Now the important relation existing between the faces of a crystal is that the denominators h, k and l are always rational whole numbers, rarely exceeding 6, and usually 0, 1, 2 or 3. Written in the form (hkl), h referring to the axis OX, k to OY, and l to OZ, they are spoken of as the indices (Millerian indices) of the face. Thus of a face parallel to the plane ABC the indices are (111), of ABe they are (112), and of fg C  (23 1 ). The indices are thus inversely proportional to the intercepts, and the law of rational intercepts is often spoken of as the "law of rational indices."

The angular position of a face is thus completely fixed by its indices; and knowing the angles between the axial planes and the parametral plane all the angles of a crystal can be calculated when the indices of the faces are known.

Although any set of edges formed by the intersection of three planes may be chosen for the crystallographic axes, it is in practice usual to select certain edges related to the symmetry of the crystal, and usually coincident with axes of symmetry; for then the indices will be simpler and all faces of the same simple form will have a similar set of indices. The angles between the axes and the ratio of the lengths of the parameters OA: OB: OC (usually given as a: b: c) are spoken of as the "elements" of a crystal, and are constant for and characteristic of all crystals of the same substance.

The six systems of crystal forms, to be enumerated below, are defined by the relative inclinations of the crystallographic axes and the lengths of the parameters. In the cubic system, for example, the three crystallographic axes are taken parallel to the three tetrad axes of symmetry, i.e. parallel to the edges of the cube (fig. 5) or joining the opposite corners of the octahedron (fig. 3), and they are therefore all at right angles; the parametral plane (111) is a face of the octahedron, and the parameters are all of equal length. The indices of the eight faces of the octahedron will then be (111), ( 1 11), (1 1 1), ( 1 1 1), (11 1 ), ( 1 1 1 ), (1 1 1 ), ( 1 1 1 ). The symbol {111} indicates all the faces belonging to this simple form. The indices of the six faces of the cube are (100), (010), (001), ( 1 00), (0 1 0), (00 1 ); here each face is parallel to two axes, i.e. intercepts them at infinity, so that the corresponding indices are zero.

(d) Zones.

An important consequence of the law of rational intercepts is the arrangement of the faces of a crystal in zones. All faces, whether they belong to one or more simple forms, which intersect in parallel edges are said to lie in the same zone. A line drawn through the centre O of the crystal parallel to these edges is called a zone-axis, and a plane perpendicular to this axis is called a zone-plane. On a cube, for example, there are three zones each containing four faces, the zone-axes being coincident with the three tetrad axes of symmetry. In the crystal of zircon (fig. 88) the eight prism-faces a, m, &c. constitute a zone, denoted