Page:EB1911 - Volume 04.djvu/971

 Verses in which neither of these caesuras occurs are considered faulty. On the other hand, secondary or subsidiary caesuras are found in both Greek and Latin; thus, a trithemimeral (after the 3rd half-foot) is combined with the hephthemimeral, which divides the verse into two unequal parts. A caesura is often called masculine when it falls after a long, feminine when it falls after a short syllable.

The best treatise on Greek and Latin metre for general use is L. Müller, Die Metrik der Griechen und Römer (1885); see also the article.

CAFFEINE, or (1.3.7 trimethyl 2.6 dioxypurin), C8H10N4O2·H2O, a substance found in the leaves and beans of the coffee tree, in tea, in Paraguay tea, and in small quantities in cocoa and in the kola nut. It may be extracted from tea or coffee by boiling with water, the dissolved tannin precipitated by basic lead acetate, the solution filtered, excess of lead precipitated by sulphuretted hydrogen and the filtered liquid then evaporated to crystallization; or, tea is boiled with water, and the whole then evaporated to a syrup, which is mixed with slaked lime, evaporated to dryness on the water-bath and extracted with chloroform (P. Cazeneuve, Bull. de la soc. chim. de Paris, 1876–1877, 27, p. 199). Synthetically it may be prepared by the methylation of silver theobromine and silver theophyllin or by boiling heteroxanthine with methyl iodide and potash. E. Fischer and L. Ach (Berichte, 1895, 28, p. 3135) have synthesized it from dimethyl alloxan, whilst W. Traube (Berichte, 1900, 33, p. 3435) has obtained it from 1.3 diamethyl 4.5 diamino 2.6 dioxypyrimidine. On the constitution of caffeine see and also E. Fischer (Annalen, 1882, 215, p. 253).

Caffeine crystallizes in long silky needles, which are slightly soluble in cold water. It becomes anhydrous at 100°C. and melts at 234° to 235°C. It has a faint bitter taste and gives salts with mineral acids. On oxidation with nitric acid caffeine gives cholesterophane (dimethyl parabanic acid), but if chlorine water be used as the oxidant, then it yields monomethyl urea and dimethyl alloxan (E. Fischer).

CAFFIERI, JACQUES (1678–1755), French worker in metal, the most famous member of a family several of whom distinguished themselves in plastic art, was the fifth son of Philippe Caffieri (1634–1716), a decorative sculptor, who, after serving Pope Alexander VII., entered the service of Louis XIV. in 1660. An elder son of Philippe, François Charles (1667–1721), was associated with him. As a fondeur ciseleur, however, the renown of the house centred in Jacques, though it is not always easy to distinguish between his own work and that of his son Philippe (1714–1777). A large proportion of his brilliant achievement as a designer and chaser in bronze and other metals was executed for the crown at Versailles, Fontainebleau, Compiègne, Choisy and La Muette, and the crown, ever in his debt, still owed him money at his death. Jacques and his son Philippe undoubtedly worked together in the “Appartement du Dauphin” at Versailles, and although much of their contribution to the palace has disappeared, the decorations of the marble chimney-piece still remain. They belong to the best type of the Louis XV. style—vigorous and graceful in design, they are executed with splendid skill. It is equally certain that father and son worked together upon the gorgeous bronze case of the famous astronomical clock made by Passement and Danthiau for Louis XV. between 1749 and 1753. The form of the case has been much criticized, and even ridiculed, but the severest critics in that particular have been the readiest to laud the boldness and freedom of the motives, the jewel-like finish of the craftsmanship, the magnificent dexterity of the master-hand. The elder Caffieri was, indeed, the most consummate practitioner of the style rocaille, which he constantly redeemed from its mannered conventionalism by the ease and mastery with which he treated it. From the studio in which he and his son worked side by side came an amazing amount of work, chiefly in the shape of those gilded bronze mounts which in the end became more insistent than the pieces of furniture which they adorned. Little of his achievement was ordinary; an astonishingly large proportion of it is famous. There is in the Wallace collection (Hertford House, London) a commode from the hand of Jacques Caffieri in which the brilliance and spontaneity, the sweeping boldness and elegance of line that mark his style at its best, are seen in a perfection hardly exceeded in any other example. Also at Hertford House is the exceptionally fine lustre which was a wedding present from Louis XV. to Louise Elizabeth of France. After Jacques’ death his son Philippe continued to work for the crown, but had many private clients. He made a great cross and six candlesticks for the high altar of Notre Dame, which disappeared in the revolution, but similar work for Bayeux cathedral still exists. A wonderful enamelled toilet set which he executed for the Princess of Asturias has also disappeared. Philippe’s style was gradually modified into that which prevailed in the third quarter of the 18th century, since by 1777, when he died, the taste for the magnificent mounts of his early days had passed away. Like his father, he drew large sums from the crown, usually after giving many years’ credit, while many other years were needed by his heirs to get in the balance of the royal indebtedness. Philippe’s younger brother, Jean Jacques Caffieri (1725–1792), was a sculptor, but was sufficiently adept in the treatment of metals to design the fine rampe d’escalier which still adorns the Palais Royal.

CAFTAN, or (a Turkish word, also in use in Persia), a tunic or under-dress with long hanging sleeves, tied with a girdle at the waist, worn in the East by persons of both sexes. The caftan was worn by the upper and middle classes in Russia till the time of Peter the Great, when it was generally discarded.

CAGLI, a town and (with Pergola) an episcopal see of the Marches, Italy, in the province of Pesaro and Urbino, 18 m. S. of the latter town by rail, and 830 ft. above sea-level. Pop. (1901) of town, 4628; commune, 12,533. The church of S. Domenico contains a good fresco (Madonna and saints) by Giovanni Santi, the father of Raphael. The citadel of the 15th century, constructed by Francesco di Giorgio Martini of Siena, is on the S.E. of the modern town. Cagli occupies the site of an ancient vicus (village) on the Via Flaminia, which seems to have borne the name Cale, 24 m. N. of Helvillum (mod. Sigillo) and 18 m. S.W. of Forum Sempronii (mod. Fossombrone). Below the town to the north is a single arched bridge of the road, the arch having the span of 38 ft. (See G. Mochi, Storia di Cagli, Cagli, 1878.) About 5 m. to the N.N.W. of Cagli and 2 m. W. of the Via Flaminia at the mod. Acqualagna is the site of an ancient town; the place is now called piano di Valeria, and is scattered with ruins. Inscriptions show that this was a Roman municipium, perhaps Pitinum Mergens (Corp. Inscr. Lat. xi. [Berlin, 1901] p. 876). Three miles north of Acqualagna the Via Flaminia, which is still in use as the modern high-road, traverses the Furlo Pass, a tunnel about 40 yds. long, excavated by Vespasian in 77, as an inscription at the north end records. There is another tunnel at lower level, which belongs to an earlier date; this seems to have been in use till the construction of the Roman road, which at first ran round the rock on the outside, until Vespasian cut the tunnel. In repairing the modern road just outside the south entrance to the tunnel, a stratum of carbonized corn, beans, &c., and a quantity of burnt wood, stones, tiles, pottery, &c., was found under and above the modern road, for a distance of some 500 yds. This débris must have belonged to the castle of Petra Pertusa, burned by the Lombards in 570 or 571 on their way to Rome. The castle itself is mentioned by Procopius (Bell. Goth. ii. 11, iii. 6, iv. 28, 34). Here also was found the inscription of 295, relating to the measures taken to suppress brigandage in these parts. (See .)

See A. Vernarecci in Notizie degli Scavi, 1886, 411 (cf. ibid. 227); ''Corp. Inscr. Lat.'' (Berlin, 1901), Nos. 6106, 6107.

CAGLIARI (anc. Carales), the capital of the island of Sardinia, an archiepiscopal see, and the chief town of the province of Cagliari, which embraces the southern half of the island. It is 270 m. W.S.W. of Naples, and 375 m. south of Genoa by sea. Pop. (1900) of town, 48,098; of commune, 53,057. It is finely situated at the northern extremity of the Gulf of Cagliari, in the centre of the south coast of the island. The medieval town occupies a long narrow hill running N. and S. with precipitous