Page:Current Strategies for Engineering Controls in Nanomaterial Production and Downstream Handling Processes.pdf/63

 individual processes to be assessed by removing the background component [Brouwer et al. 2004; Demou et al. 2008; Peters et al. 2009]. The background measurement should be repeated after process or task evaluations. High background concentrations need to be addressed before control evaluation. The following factors can affect background data:


 * Monitoring period. In a nanomanufacturing facility, the day of the week or the time of day during the monitoring period will affect background levels since worker movement and frequency of worker operations are variable.


 * Other activities or operations around the monitored activity. Any operation, such as product harvesting or equipment maintenance, in areas outside the monitoring location could potentially influence background concentrations at the monitoring location.


 * General ventilation conditions. The layout and operation of the general ventilation system in the workplace should be considered while monitoring background concentrations. Basic ventilation data (e.g., volume of air flow, location of supply and exhaust, general air movement in the facility), including air supply source, should be collected. Additionally, variations in environmental conditions (especially humidity) need to be measured.


 * Other sources. Some equipment can produce incidental (nonprocess) nanoparticles. Examples include diesel engines, welders, gas-fired heaters, and air compressors for pulse-jet baghouses or dust collectors.

Area (or static) monitoring can also be conducted to evaluate the general air quality of workplaces. Instruments such as the CPC and impactors are suitable for this type of monitoring. Ideally, filter samples can be taken at the same location as area monitoring with direct-reading instruments to make a side-by-side comparison.

4.1.3 Air Monitoring and Filter Sampling

The selection of direct-reading instruments (Table 3) for field evaluation must cover a wide range of particle sizes. Particle diffusion occurs rapidly when nanoparticles are released in the workplace. It results in nanomaterial agglomerates because of particle collisions. For example, the average particle size (or size distribution) is larger during product transfer than right after product harvesting. Based on the data collected during initial assessment, characterization of nanomaterial emissions can be conducted with direct-reading instruments to provide higher resolutions of spatial and time variation. To evaluate control efficiency for specific processes or tasks, the sampling ports should be located as close as possible to the suspected emission sources but outside of control measures (or at a worker’s breathing zone). Filter sampling for off-line qualitative analysis must occur in parallel with real-time monitoring. Sampling duration may not be an issue for most direct-reading instruments but should be considered for filter sampling to avoid overloading. The data collected from an initial assessment can be used to determine sampling time and flow rate for filter samples.

48

Current Strategies for Engineering Controls in Nanomaterial Production and Downstream Handling Processes