Page:Current Strategies for Engineering Controls in Nanomaterial Production and Downstream Handling Processes.pdf/35

 Several studies have been conducted of respirator media filtration performance against nanoparticles. Many employers provide filtering facepiece respirators (FFRs) due to their common availability and low cost. One study of N95 FFRs showed penetration levels by nanoparticles in the size range of ~30 to 70 nm, which exceeded the 5% level allowed by NIOSH [Balazy et al. 2006]. A later study used two test methods (challenges using a monodisperse aerosol and a polydisperse aerosol similar to the NIOSH certification test) and compared particle penetration of N-95 FFRs [Rengasamy et al. 2007]. Those authors found that a monodisperse aerosol challenge test using particles from 20 nm to 400 nm in diameter resulted in a MPPS near 40 nm. The monodisperse test found that two respirators exceeded the NIOSH 5% allowed penetration, but the exceedance was not statistically significant, while the polydisperse challenge produced penetration levels from 0.61% to 1.24%. The NIOSH-allowed penetration level of < 0.03% was not exceeded by P100 FFRs, but two nanoparticle test aerosols did exceed 1% penetration for two N99 FFRs [Eninger et al. 2008; Rengasamy et al. 2009]. Five models of N95 and two models of P100 FFRs challenged with 4–30-nm monodisperse aerosols provided approved levels of protection [Rengasamy et al. 2008]. Rengasamy et al. [2009] tested two models each of N95 and P100 respirators with monodisperse aerosols in the 4–30-nm range and the 20–400-nm range. The penetration levels were less than the NIOSH-allowed levels of < 5% and < 0.03% across all test methods used. The penetration was < 4.28% for the N95 respirators and < 0.009% for the P100 respirators at the MPPS range of 30–60 nm.

NIOSH-certified FFRs have been shown to provide “expected levels of filtration efficiency against polydisperse and monodisperse aerosols > 20 nm in size” [Rengasamy and Eimer 2011]. A study showed that eight commercially purchased models of NIOSH-approved N95 and P100 and CE-marked FFR models “provided expected levels of laboratory performance against nanoparticles” [Rengasamy et al. 2009].

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Current Strategies for Engineering Controls in Nanomaterial Production and Downstream Handling Processes