Page:Chance, love, and logic - philosophical essays (IA chancelovelogicp00peir 0).pdf/286

 two spheres described round a particle as their center, the radius of the larger being so great as to include all the particles whose action upon the center is sensible, while the radius of the smaller is so large that a good many molecules are included within it. The possibility of describing such a sphere as the outer one implies that the attraction of the particles varies at some distances inversely as some higher power of the distance than the cube, or, to speak more clearly, that the attraction multiplied by the cube of the distance diminishes as the distance increases; for the number of particles at a given distance from any one particle is proportionate to the square of that distance and each of these gives a term of the virial which is the product of the attraction into the distance. Consequently, unless the attraction multiplied by the cube of the distance diminished so rapidly with the distance as soon to become insensible, no such outer sphere as is supposed could be described. However, ordinary experience shows that such a sphere is possible; and consequently there must be distances at which the attraction does thus rapidly diminish as the distance increases. The two spheres, then, being so drawn, consider the virial of the central particle due to the particles between them. Let the density of the substance be increased, say, N times. Then, for every turn, Rr, of the virial before the condensation, there will be N terms of the same magnitude after the condensation. Hence, the virial of each particle will be proportional to the density, and the equation of the virial becomes

aθ = P(V̄) + c/([=V]).